Tuesday, 4 July 2006 - 12:00 AM
FERRP-53

Critical behavior at the isotropic to nematic phase transition in a bent-core liquid crystal

David Wiant1, Strahinja Stojadinovic1, Krishna Neupane1, Sunil Sharma1, Katalin Fodor-Csorba2, Antal Jakli3, James Gleeson1, and Samual Sprunt1. (1) Physics Department, Kent State University, 105 Smith Hall, Kent, OH 44242, (2) Liquid Crystals Department, Research Institute for Solid State Physics and Optics, Hungarian Academy of Sciences, P. O. Box 49, Budapest, H-1525, Hungary, (3) Liquid Crystal Institute, Kent State University, Kent, OH 44242

Magnetic birefringence and dynamic light scattering measurements of orientational order parameter fluctuations at the isotropic-nematic phase transition of a bent-core liquid crystal reveal a pretransitional temperature dependence consistent with the standard Landau-deGennes mean field theory. However, the transition in the bent-core compound is more weakly first-order (TNI-T* ~0.4oC), the leading Landau coefficient is ~30 times lower, the viscosity associated with nematic order fluctuations is ~10 times higher, and the density change is ~10 times lower than typically observed in calamitic (rod-shaped)liquid crystals. One consistent explanation for these anomalies is an optically isotropic phase composed of complexes of bent-core molecules. Also, we will present preliminary magnetic birefringence and density measurements at temperatures above the nematic-isotropic transistion which support the existence of such an optically isotropic clustered state.


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